SINTESIS LAPISAN TIPIS TiO2:(F+In) PADA SUBSTRAT KACA DENGAN METODE SPIN-COATING SEBAGAI BAHAN SEL SURYA
DOI:
https://doi.org/10.31764/orbita.v%25vi%25i.4655Keywords:
Sintesis Lapisan Tipis, TiO2, (F In), Metode Spin-coating, Sel Surya.Abstract
ABSTRAK
Telah dilakukan penelitian sintesis lapisan tipis TiO2 dengan doping campuran Fluorin dan Indium. Tujuan penelitian ini untuk menghasilkan lapisan tipis yang baik digunakan sebagai salah satu komponen pada sel surya yaitu lapisan absorben. Sintesis lapisan tipis menggunakan metode spin-coating dengan bantuan alat centrifuge yang dimodifikasi. Penelitian ini dilaksanakan di Laboratorium Kimia Dasar dan Kimia Organik, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Mataram. Jenis penelitian ini adalah penelitian eksperimen murni dengan data dianalisis secara deskriptif. Proses sintesis lapisan tipis terdiri dari beberapa tahapan yaitu 1). Persiapan substrat, 2). Pembuatan larutan sol-gel, 3). Deposisi lapisan tipis, dan 4). Pemanasan sampel lapisan tipis. Sampel lapisan tipis diberikan tiga perlakuan berbeda yang terdiri dari 1). Konsentrasi larutan, 2). Jumlah lapisan, dan 3). Variasi suhu pemanasan sampel. Berdasarkan penelitian yang sudah dilakukan didapatkan bahwa semakin besar konsentrasi doping yang digunakan maka semakin gelap permukaan sampel lapisan tipis yang dihasilkan.
Â
Kata kunci: sintesis lapisan tipis; TiO2:(F+In); metode spin-coating; sel surya.
Â
ABSTRACT
Research on the synthesis of TiO2 thin films with doping mixture of Fluorine and Indium has been carried out. The aim of this research is to produce a thin film which is suitable for use as a component of solar cells, namely the absorbent layer. Synthesis of thin films using the spin-coating method with the help of a modified centrifuge. This research was conducted at the Laboratory of Basic Chemistry and Organic Chemistry, Faculty of Mathematics and Natural Sciences, Mataram University. This type of research is pure experimental research with data analyzed descriptively. The thin layer synthesis process consists of several stages, namely 1). Substrate preparation, 2). Preparation of sol-gel solution, 3). Thin layer deposition, and 4). Heating the thin layer sample. The thin layer sample was given three different treatments consisting of 1). The concentration of the solution, 2). Number of layers, and 3). Variation in sample heating temperature. Based on the research that has been done, it was found that the greater the doping concentration used, the darker the surface of the resulting thin layer sample.
Â
Keywords: synthesis thin film; TiO2:(F+In); spin-coating method; solar cells
References
Abegunde, O. O., et al. (2019). Overview of Thin Film Deposition Techniques. AIMS Materials Science, 6(2), 174-199.
Amalia, A., & Tamamy, A. J. (2019). Kesiapan Masyarakat Semarang dalam Pemanfaatan Potensi Energi Surya sebagai Sumber Energi Alternatif Berkelanjutan. SAINTEK: Jurnal ilmiah Sains dan Teknologi Industri, 2(2), 39-48.
Arini, et al. (2017). Pengaruh Waktu Deposisi dan Temperatur Substrat Terhadap Pembuatan Kaca Konduktif FTO (Fluorine doped Tin Oxide)[The Influence of Deposition Time and Substrate Temperature in Manufacturing Process of FTO (Fluorine doped Tin Oxide) Conductive Glass]. Metalurgi, 32(1), 1-8.
Bautista-Ruiz, J., Aperador, W., & Olaya, J. J. (2018). Effect of Centrifugal Speed on the Anticorrosive Properties of Bismuth-Silicon Coatings by Sol-Gel on 316L Substrates. Rasayan Journal of Chemistry, 11(2), 597-607.
Bierwagen, O. (2015). Indium oxide—a transparent, wide-band gap semiconductor for (opto) electronic applications. Semiconductor Science and Technology, 30(2), 024001.
Bredas, J.L., Sargent, E. H., & Scholes, G. D. (2017). Photovoltaic Concepts Inspired by Coherence Effects in Photosynthetic System. Nature Materials, 16(1), 35-44.
Buwarda, S. (2019). AZTS dengan Metode Sol-Gel sebagai Lapisan Buffer Bebas Cadmium pada Sel Surya CZTS. Jurnal Keteknikan dan Sains (JUTEKS), 2(1), 1-7.
Chandramohan, A., et. al. (2017). Model For Large Area Monolayer Coverage of Polystyrene Nanosphere by Spin Coating. Scientific Reports. 7, 1-8.
Doyan, A., Fitri, S. A., & Ahzan, S. (2017). Crystal structure characterization of thin layer zinc oxide. In IOP Conference Series: Materials Science and Engineering (Vol. 196, No. 1, p. 012004). IOP Publishing.
Doyan, A., Susilawati, S., & Muliyadi, L. (2020). Synthesis of Tin Oxide Thin Layer by Doping Aluminum, Fluorine, and Indium Using Sol-Gel Spin Coating Technique. JPPIPA (Jurnal Penelitian Pendidikan IPA), 7(1), 11-14.
Fisicaro, G., et al. (2019). Wet Environment Effects for Ethanol and Water Adsorption on Anatase TiO2 (101) Surfaces. The Journal of Physical Chemistry C, 124(4), 2406-2419.
Gondal, M. A., Ilyas, A. M., & Baig, U. (2016). Facile Synthesis of Silicon Carbide-Titanium Dioxide Semiconducting Nanocomposite Using Pulsed Laser Ablation Technique and its Performance in Photovoltaic Dye Sensitized Solar Cell and Photocatalytic Water Purification. Applied Surface Science, 378, 8-14.
Hakim, S., Doyan, A., & Susilawati, L. M. (2019). Synthesis Thin Films SnO2with Doping Indium by Sol-Gel Spin Coating. Material Sciences.
Husain, A. A., et al. (2018). A Review of Transparent Solar Photovoltaic Technologies. Renewable and Sustainable Energy Reviews, 94, 779-791.
Ilican, S., Caglar, Y., & Caglar, M. (2008). Preparation and Characterization of ZnO Thin Films Deposited by Sog-Gel Spin Coating Method. Journal of Optoelectronics and Advanced Materials, 10(10), 2578-2583.
International Energy Agency. (2019). World Energy Outlook 2019. Prancis: IEA.
Jomekian, A., et al. (2017). High speed spin coating in fabrication of Pebax 1657 based mixed matrix membrane filled with ultra-porous ZIF-8 particles for CO 2/CH 4 separation. Korean Journal of Chemical Engineering, 34(2), 440-453.
Luo, M., et al. (2019). High-Performance Partially Printed Hybrid CMOS Inverters Based on Indium-Zinc-Oxide and Chirality Enriched Carbon Nanotube Thin-Film Transistors.Weinheim: WILEY-VCH Verlag GmbH & Co.
Maddu, A., et al. (2018). Struktur dan Sifat Optik Film ZnO Hasil Deposisi Dengan Teknik Spin-Coating Melalui Proses Sol-Gel. Jurnal Sains Materi Indonesia, 7(3), 85-90.
Muliyadi, L., Doyan, A., Susilawati, S., & Hakim, S. (2019). Synthesis of SnO2 Thin Layer with a Doping Fluorine by Sol-Gel Spin Coating Method. Jurnal Penelitian Pendidikan IPA, 5(2), 175-178.
Munandar, H., Doyan, A., & Susilawati, S. (2020). Synthesis of SnO2 Thin Coatings by Indium and Aluminum Mixed Doping using the Sol-Gel Spin-Coating Technique. Jurnal Penelitian Pendidikan IPA, 6(2), 152-156.
Nayak, P. K., et al. (2019). Photovoltaic Solar Cell Technology: Analysing the State of The Art. Nature Reviews Materials, 4(4), 269.
Ras, D. A., Kirchart, T., & Rau, U. (2016). Advanced Characterization Techniques for Thin Film Solar Cells. USA: John Wiley & Sons.
Riyanti, R. S. (2019). Pengaruh Kecepatan Putaran Spin Coating Terhadap Performansi Perovskite Solar Cell. Jurnal Mahasiswa TEUB, 7(4).
Sa'adah, H., & Nurhasnawati, H. (2017). Perbandingan pelarut etanol dan air pada pembuatan ekstrak umbi bawang tiwai (Eleutherine americana Merr) menggunakan metode maserasi.
Jurnal ilmiah manuntung, 1(2), 149-153.
Sariroh, A. (2018). Pengaruh Kecepatan dan Waktu Putar Spin Coating Terhadap Ketebalan Lapisan Tipis Material Berbasis Polimer Pmma (Polymethyl Methacrylate). Inovasi Fisika Indonesia, 7(1), 1-4.
Setiawan, W., Hermawan, R., & Suardi, S. (2018). Analisa Potensi Angin Dan Cahaya Matahari Sebagai Alternatif Sumber Tenaga Listrik Di Wilayah Laut Sawu. JST (Jurnal Sains Terapan), 4(1), 57-62.
Setyani, A., & Wibowo, E. A. P. (2017). Pengaruh Pelarut terhadap Karakteristik Nanopartikel Titanium Dioksida (TiO2). Jurnal Ilmiah Sains, 17(1), 26-29.
Sutha, S., et al. (2017). Transparent alumina based superhydrophobic self–cleaning coatings for solar cell cover glass applications. Solar Energy Materials and Solar Cells, 165, 128-137.
Syahvalensi, N., Rokhmat, M., & Wibowo, E. (2019). Pengaruh Penambahan Karbon pada Fotokatalis Berbahan Dasar TiO_2 untuk Mendegradasi Methylene Blue. In eProceedings of Engineering, 6(1).
Wibowo, E. A. P. (2017). Sintesis Komposit N- TiO_2/Bentonit dan Karakterisasi Menggunakan FTIP. JTT (Jurnal Teknologi Terpadu), 5(1), 96-99.
Yu, X., et al. (2017). Recent Advances in the Synthesis and Energy Applications of TiO_2-Graphene Nanohybrids. Solar Energy Materials and Solar Cells, 172, 252-269.
Zhang, Y., et. al. (2017). Mesocrystalline TiO_2 Nanosheet Arrays with Exposed {001} Facets: Synthesis Via Topotactic Transformation and Applications in Dye-Sensitized Solar Cells. Nano Research, 10(8), 2610-2625.
Zhi, J., & Zhang, L. Z. (2018). Durable superhydrophobic surface with highly antireflective and self-cleaning properties for the glass covers of solar cells. Applied Surface Science, 454, 239-248.
Downloads
Published
Issue
Section
License
The copyright of the received article shall be assigned to the journal as the publisher of the journal. The intended copyright includes the right to publish the article in various forms (including reprints). The journal maintains the publishing rights to the published articles.
ORBITA: Jurnal Pendidikan dan Ilmu Fisika is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.